Dioctyl adipate(DOA)

Basic information

  • Product Name:Dioctyl adipate(DOA)
  • CasNo.:103-23-1
  • MF:C22H42O4
  • MW:370.573

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:-67 °C
  • Packing:colorless or light yellow oily liquid with special odour
  • Throughput:
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Product Details

CasNo: 103-23-1

MF: C22H42O4

Appearance: colorless or light yellow oily liquid with special odour

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  • Molecular Formula:C22H42O4
  • Molecular Weight:370.573
  • Appearance/Colour:colorless or light yellow oily liquid with special odour 
  • Vapor Pressure:8.35E-06mmHg at 25°C 
  • Melting Point:-67 °C 
  • Refractive Index:n20/D 1.447(lit.)  
  • Boiling Point:374.4 °C at 760 mmHg 
  • Flash Point:168.9 °C 
  • PSA:52.60000 
  • Density:0.928 g/cm3 
  • LogP:6.06600 

Bis(2-ethylhexyl) adipate(Cas 103-23-1) Usage

Production Methods

DEHA is manufactured by esterification of adipic acid and 2-ethylhexanol.

Air & Water Reactions

Bis(2-ethylhexyl) adipate slowly hydrolyzes. Insoluble in water.

Reactivity Profile

Bis(2-ethylhexyl) adipate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250]. Bis(2-ethylhexyl) adipate is incompatible with oxidizing materials and water. Bis(2-ethylhexyl) adipate is also incompatible with nitrates.

Health Hazard

Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation.

Fire Hazard

Behavior in Fire: Use water spray to cool exposed containers.

Flammability and Explosibility

Nonflammable

Safety Profile

Moderately toxic by intravenous route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. An eye and skin irritant. Questionable carcinogen with experimental carcinogenic data. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.

Definition

ChEBI: A diester resulting from the formal condensation of the carboxy groups of adipic acid with 2-ethylhexan-1-ol. It is used as a plasticiser in the preparation of various polymers.

General Description

Colorless to straw-colored liquid with a mild odor. Floats on water.

InChI:InChI=1/C22H42O4/c1-5-9-13-19(7-3)17-25-21(23)15-11-12-16-22(24)26-18-20(8-4)14-10-6-2/h19-20H,5-18H2,1-4H3/t19-,20+

103-23-1 Relevant articles

Nano-SO42-/TiO2catalyzed eco-friendly esterification of dicarboxylic acids

Ji, Xianbing,Chen, Yinxia,Shen, Zuoyuan

, p. 5769 - 5772 (2014)

Nano-SO42-/TiO2 was prepared by wet impr...

Exceptionally active and reusable nanobiocatalyst comprising lipase non-covalently immobilized on multi-wall carbon nanotubes for the synthesis of diester plasticizers

Szelwicka, Anna,Boncel, S?awomir,Jurczyk, Sebastian,Chrobok, Anna

, p. 41 - 47 (2019)

A new method for the synthesis of dicarb...

Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers

Tashi, Maryam,Shafiee, Behnaz,Sakamaki, Yoshie,Hu, Ji-Yun,Heidrick, Zachary,Khosropour, Ahmad R.,Beyzavi, M. Hassan

, p. 37835 - 37840 (2018)

The combination of continuous flow techn...

Oxidation of cyclohexanone and/or cyclohexanol catalyzed by Dawson-type polyoxometalates using hydrogen peroxide

Dermeche, Leila,Idrissou, Yasmina,Mazari, Tassadit,Moudjahed, Mohammed,Rabia, Cherifa

, (2022/03/07)

The oxidation of cyclohexanone, cyclohex...

Lubricant base oil and ester compounds

-

Paragraph 0099; 0100, (2019/06/29)

[Problem] To provide: an ester compound ...

103-23-1 Process route

Adipic acid
124-04-9

Adipic acid

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

adipic acid mono-2-ethylhexyl ester
4337-65-9

adipic acid mono-2-ethylhexyl ester

di(2-ethylhexyl)adipate
103-23-1

di(2-ethylhexyl)adipate

Conditions
Conditions Yield
With hydrogenchloride; In water; for 4h; Reflux;
46 %Chromat.
49 %Chromat.
Adipic acid
124-04-9

Adipic acid

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

di(2-ethylhexyl)adipate
103-23-1

di(2-ethylhexyl)adipate

Conditions
Conditions Yield
With triflic acid on silica-encapsulated superparamagnetic iron oxide nanoparticles; In neat (no solvent); at 90 ℃; for 0.333333h; Time; Reagent/catalyst; Catalytic behavior; Flow reactor; Green chemistry;
96%
In 5,5-dimethyl-1,3-cyclohexadiene; at 160 ℃; for 2h;
90%
With Candida antarctica lipase B; In cyclohexane; at 45 ℃; for 24h;
66%
With sulfuric acid; benzene;

103-23-1 Upstream products

  • 124-04-9
    124-04-9

    Adipic acid

  • 104-76-7
    104-76-7

    2-Ethylhexyl alcohol

  • 4337-65-9
    4337-65-9

    adipic acid mono-2-ethylhexyl ester

  • 108-94-1
    108-94-1

    cyclohexanone

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    2-octyl-cyclopentanone

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    120587-85-1

    5-Methyl-4-methylene-hexahydro-pentalen-1-one

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    825-25-2

    2-cyclopentylidenecyclopentan-1-one