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CasNo: 103-23-1
MF: C22H42O4
Appearance: colorless or light yellow oily liquid with special odour
Production Methods |
DEHA is manufactured by esterification of adipic acid and 2-ethylhexanol. |
Air & Water Reactions |
Bis(2-ethylhexyl) adipate slowly hydrolyzes. Insoluble in water. |
Reactivity Profile |
Bis(2-ethylhexyl) adipate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250]. Bis(2-ethylhexyl) adipate is incompatible with oxidizing materials and water. Bis(2-ethylhexyl) adipate is also incompatible with nitrates. |
Health Hazard |
Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. |
Fire Hazard |
Behavior in Fire: Use water spray to cool exposed containers. |
Flammability and Explosibility |
Nonflammable |
Safety Profile |
Moderately toxic by intravenous route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. An eye and skin irritant. Questionable carcinogen with experimental carcinogenic data. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes. |
Definition |
ChEBI: A diester resulting from the formal condensation of the carboxy groups of adipic acid with 2-ethylhexan-1-ol. It is used as a plasticiser in the preparation of various polymers. |
General Description |
Colorless to straw-colored liquid with a mild odor. Floats on water. |
InChI:InChI=1/C22H42O4/c1-5-9-13-19(7-3)17-25-21(23)15-11-12-16-22(24)26-18-20(8-4)14-10-6-2/h19-20H,5-18H2,1-4H3/t19-,20+
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Adipic acid
2-Ethylhexyl alcohol
adipic acid mono-2-ethylhexyl ester
di(2-ethylhexyl)adipate
Conditions | Yield |
---|---|
With
hydrogenchloride;
In
water;
for 4h;
Reflux;
|
46 %Chromat. 49 %Chromat. |
Adipic acid
2-Ethylhexyl alcohol
di(2-ethylhexyl)adipate
Conditions | Yield |
---|---|
With
triflic acid on silica-encapsulated superparamagnetic iron oxide nanoparticles;
In
neat (no solvent);
at 90 ℃;
for 0.333333h;
Time;
Reagent/catalyst;
Catalytic behavior;
Flow reactor;
Green chemistry;
|
96% |
In
5,5-dimethyl-1,3-cyclohexadiene;
at 160 ℃;
for 2h;
|
90% |
With
Candida antarctica lipase B;
In
cyclohexane;
at 45 ℃;
for 24h;
|
66% |
With
sulfuric acid; benzene;
|
Adipic acid
2-Ethylhexyl alcohol
adipic acid mono-2-ethylhexyl ester
cyclohexanone
2-octyl-cyclopentanone
5-Methyl-4-methylene-hexahydro-pentalen-1-one
2-cyclopentylidenecyclopentan-1-one